Continuous flow systems for multicatalytic processes based on supported ionic liquids

  1. PERIS SALOM, EDGAR
Dirigée par:
  1. Eduardo García Verdugo Directeur/trice
  2. Santiago V. Luis Directeur/trice

Université de défendre: Universitat Jaume I

Fecha de defensa: 28 janvier 2019

Jury:
  1. Ernesto de Jesús Alcañiz President
  2. Emilia Tojo Suárez Secrétaire
  3. Carmen Nájera Domingo Rapporteur
  4. Miguel Yus Astiz Rapporteur
  5. Michelangelo Gruttadauria Rapporteur

Type: Thèses

Teseo: 579917 DIALNET lock_openTDX editor

Résumé

This Doctoral Thesis is framed in the area of Sustainable Chemistry and more specifically in the field of continuous flow chemistry. The main objective has been the design and development of new continuous multicatalytic systems based on the use of supported ionic liquids, materials with very interesting catalytic properties. This objective has been applied to C-C bond forming reactions such as cyanosilylation, Strecker reaction or Negishi cross-couplings; whose products mean key synthetic intermediates in several processes in organic synthesis, specially in Fine and Pharmaceutical Chemistry. Telescopic processes and divergent syntheses have been succesfully achieved under continuous flow conditions. In addition, the novel additive manufacturing 3D printing technology has been introduced for the potential obtaining of continuous flow catalytic reactors.